Heating to 400°C-450°C converts amethyst to citrine and at 500°C-575°C colour is intensified to orange yellow to reddish brown. These are often called burned amethysts. On further heating the colour may be bleached giving rise to a milky opalescence (Frondel, 1962).
On irradiation, amethystine colour may be reinstalled and it can be reversed on heating to obtain pale citrine colour, but not those converted to deep yellow-orange brown citrine.
Some carefully heated stones produce a bicoloured ametrine, consisting of alternate sectors of violet and yellow colour. On controlled heating some amethyst from Minas Gerais, Brazil produce a green coloured quartz termed as prasiolite. The colour is due to the conversion of Fe3+ to Fe2+. Green quartz is synthesized by doping it with iron (Fe2+) in reducing atmosphere.
Amethyst is mined in India, Brazil, Uruguay, Bolivia and Argentina and some African countries. Generally, amethyst from South America tends to be available in larger sizes than African amethyst but amethyst from Africa has the reputation for having better, more saturated, color in small sizes. Very dark amethyst, mostly in small sizes, is also mined in Australia.
Indian Occurence
Large deposits of zoned, rather too dark and nearly opaque amethyst are found in the granitic terrains around Hyderabad city. Some of the localities in this region are Shemsabad, Palmcut, Nagumpally, Bekonenpett, Sadashivpett and Bowenpalle. Amethyst is also found in Medak Mehboonagar and Warangal areas in Andhra Pradesh. Fine amethyst is known to occur in Kangayam (11°00':77°34'),
Tamil Nadu. In Kerala it is found at Kollengode (10°37':76°41') and also at Mundur in Mysore district, Kamataka. It is however, difficult to record the sporadic occurrence of amethyst geodes in the DT terrain of Gujarat and Maharashtra.
In Orissa it is found in Maribahal-Tetalkunti in Bolangir district. In addition to the indigenous material, India imports rock crystal, amethyst and citrine from Brazil and African countries for faceting.