Absorption spectra of rubies reveal the characteristic doublet at 694.2 and 692.8nm. In the small hand spectroscope it may appear like a single line. The other lines are at 668, 695.5, 476.5, 475 and 468.5 nm.
Pleochroism is quite distinct in rubies; Therefore, the best shade of colour is obtained when the table is cut parallel to the basal plane. In this direction, however, ruby is nonpleochroic and may be confused for a red spinel. It can be further ascertained by observing the stone in conoscopic condition when it reveals uniaxial interference figure. Colour zoning is common in ruby. Colour bands and growthlines run in straight lines with hexagonal kinks or colour may occur in patches, but the bands and growth lines are curved in synthetic Vemeuil ruby under magnification.
The presence of rutile needles only in certain spots provides a confirmatory test for natural stones . Higher concentration of needles produces undesirable pattern of silk. For the production of asterism needles have to be dense and uniformly distributed. Existence of parting planes or twinning furnishes another testimony for natural stone. Some flux grown synthetic corundums, however, may also exhibit 2-3 sets of bands known as plato lines appearing like parting planes (Webster, 1994). These intersect at 60° and 120° when viewed in the direction of optic axis.
In natural corundum when two sets of polysynthetic twinning bands parallel to rhombohedron are seen, they intersect nearly at right angles (86°04' and 93°56') and this direction does not coincide with c axis/optic axis. Often long needles of uncoloured ex solved boehmite [y-AlO(OH), orthorhombic, RI .... 1.65, d .... 0.015] may be seen concentrated along composition planes. Similarly exsolved haematite platelets may be seen along basal parting planes. Presence of boehmite, often together with diaspore [a-AlO(OH), orthorhombic,RI .... 1.71, d .... 0.04], also has one more significance. Boehmite and diaspore are seen only in unheated natural corundum.
In heat-treated corundum they get dehydrated. Their presence can be determined with the help of Infrared spectroscopy (Smithet al. 1997). Zircon , apatite, spinel, garnet, mica and iron ore and rutile needles are some of the common inclusions found in ruby as well as sapphire.